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Comparison of selenophene and thienothiophene incorporation into pentacyclic lactam-based conjugated polymers for organic solar cells

Kroon, Renee and Melianas, Armantas and Zhuang, Wenliu and Bergqvist, Jonas and Mendaza, Amaia Diaz de Zerio and Steckler, Timothy T. and Yu, Liyang and Bradley, Siobhan J. and Musumeci, Chiara and Gedefaw, Desta and Nann, Thomas and Amassian, Aram and Müller, Christian and Inganäs, Olle and Andersson, Mats R. (2015) Comparison of selenophene and thienothiophene incorporation into pentacyclic lactam-based conjugated polymers for organic solar cells. Polymer Chemistry, 6 (42). pp. 7402-7409. ISSN 1759-9954

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Abstract

In this work, we compare the effect of incorporating selenophene versus thienothiophene spacers into pentacyclic lactam-based conjugated polymers for organic solar cells. The two cyclic lactam-based copolymers were obtained via a new synthetic method for the lactam moiety. Selenophene incorporation results in a broader and red-shifted optical absorption while retaining a deep highest occupied molecular orbital level, whereas thienothienophene incorporation results in a blue-shifted optical absorption. Additionally, grazing-incidence wide angle X-ray scattering data indicates edge- and face-on solid state order for the selenophene-based polymer as compared to the thienothiophene-based polymer, which orders predominantly edge-on with respect to the substrate. In polymer : PC71BM bulk heterojunction solar cells both materials show a similar open-circuit voltage of ∼0.80–0.84 V, however the selenophene-based polymer displays a higher fill factor of ∼0.70 vs. ∼0.65. This is due to the partial face-on backbone orientation of the selenophene-based polymer, leading to a higher hole mobility, as confirmed by single-carrier diode measurements, and a concomitantly higher fill factor. Combined with improved spectral coverage of the selenophene-based polymer, as confirmed by quantum efficiency experiments, it offers a larger short-circuit current density of ∼12 mA cm−2. Despite the relatively low molecular weight of both materials, a very robust power conversion efficiency ∼7% is achieved for the selenophene-based polymer, while the thienothiophene-based polymer demonstrates only a moderate maximum PCE of ∼5.5%. Hence, the favorable effects of selenophene incorporation on the photovoltaic performance of pentacyclic lactam-based conjugated polymers are clearly demonstrated.

Item Type: Journal Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Divisions: Faculty of Science, Technology and Environment (FSTE) > School of Biological and Chemical Sciences
Depositing User: Generic Email
Date Deposited: 29 Aug 2018 13:27
Last Modified: 29 Aug 2018 13:27
URI: http://repository.usp.ac.fj/id/eprint/10889
UNSPECIFIED

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