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Synthesis, biological, spectral and thermal properties of oxovanadium (IV) complexes of N,N,S-containing ligands

Agarwal, Ram K. and Prasad, Surendra (2006) Synthesis, biological, spectral and thermal properties of oxovanadium (IV) complexes of N,N,S-containing ligands. Reviews in Inorganic Chemistry, 26 (5). pp. 471-492. ISSN 0193-4929

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Abstract

The reaction of VO2+ salts with 4[N-(2+-hydroxybenzalidene)amino/antipyrine thiosemicarbazone (HBAAPTS), 4[N-(2+-hydroxyl+-naphthalidene)amino/antipyrine thiosemicarbazone (HNAAPTS), 4[N-(cinnamalidene)amino/antipyrine thiosemicarbazone (CAAPTS) resulted in the formation of the complexes of the general composition VOX2L (X=Cl, Br, I, NO3 or NCS) and VO(ClO4)2.L.H2O (L= HBAAPTS, HNAAPTS or CAAPTS). The nature of the bonding and stereochemistry of the complexes have been deduced from elemental analysis, infrared, electronic spectra, magnetic susceptibility and conductance measurements. In all the oxovanadium(IV) complexes, the coordination number of central metal ion is five. The metal complexes were screened for their antifungal and antibacterial activities on different species of pathogenic fungi and bacteria respectively and their biopotency has been discussed.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Technology and Environment (FSTE) > School of Biological and Chemical Sciences
Depositing User: Ms Neha Harakh
Date Deposited: 16 Mar 2006 15:46
Last Modified: 04 Jul 2012 21:24
URI: http://repository.usp.ac.fj/id/eprint/3964
UNSPECIFIED

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