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Retention of stereochemistry in the extrusion of sulfur monoxide from thiirane oxides. Synthesis and thermal decomposition of cis and trans-dideuteriothiirane oxide

Aalbersberg, William G.L. and Vollhardt, K.P.C. (1977) Retention of stereochemistry in the extrusion of sulfur monoxide from thiirane oxides. Synthesis and thermal decomposition of cis and trans-dideuteriothiirane oxide. Journal of the American Chemical Society, 99 (8). pp. 2792-2794. ISSN 0002-7863

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Abstract

The synthesis of the simplest stereochemically labeled thiirane oxides, cis- and trans-dideuteriothiirane oxide via the stereospecific formation of the corresponding deuterated epoxides and thiiranes was reported. The stereochemical results of their decomposition both in the gas and solution phase was also reported. The results provide an unambiguous stereochemical test for the mode of decomposition of simple thiirane oxides. (DDA)

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Technology and Environment (FSTE) > Institute of Applied Science
Depositing User: Ms Shalni Sanjana
Date Deposited: 23 Jul 1977 22:00
Last Modified: 23 Jul 2012 22:00
URI: http://repository.usp.ac.fj/id/eprint/4891
UNSPECIFIED

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