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Synthesis, biological, spectral, and thermal investigations of cobalt(II) and nickel(II) complexes of N-isonicotinamido-2 ',4 '-dichlorobenzalaldimine

Agarwal, Ram K. and Sharma, D.K. and Singh, L. and Agarwal, H. (2006) Synthesis, biological, spectral, and thermal investigations of cobalt(II) and nickel(II) complexes of N-isonicotinamido-2 ',4 '-dichlorobenzalaldimine. Bioinorganic Chemistry and Applications, 29234 . pp. 1-9. ISSN 1565-3633

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Abstract

A new series of 12 complexes of cobalt(II) and nickel(II) with N-isonicotinamido-2′,4′-dichlorobenzalaldimine (INH-DCB) with the general composition MX2 • n(INH-DCB) [M = Co(II) or Ni(II), X = Cl− ,Br−, NO3−, NCS−, or CH3COO−, n = 2; X = ClO4−, n = 3] have been synthesized. The nature of bonding and the stereochemistry of the complexes have been deduced from elemental analyses, infrared, electronic spectra, magnetic susceptibility, and conductivity measurements. An octahedral geometry has been suggested for all the complexes. The metal complexes were screened for their antifungal and antibacterial activities on different species of pathogenic fungi and bacteria and their biopotency has been discussed.

Item Type: Journal Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Science, Technology and Environment (FSTE) > School of Biological and Chemical Sciences
Depositing User: Ms Neha Harakh
Date Deposited: 16 Mar 2006 03:30
Last Modified: 10 May 2012 07:13
URI: http://repository.usp.ac.fj/id/eprint/3968
UNSPECIFIED

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