Agarwal, Ram K. and Modi, H.R. and Prasad, Surendra (2009) Synthesis, spectral and thermal properties of some novel coordination compounds of VO(IV) derived from 4[n-(4¢-ethylbenzalidene)amino]antipyrine thiosemicarbazone and 4[n- (2¢,4¢-dimethyl benzalidene) amino]antipyrine thiosemicarbazone. Journal of the Iranian Chemical Research, 2 (3). pp. 173-182. ISSN 2008-1030
Full text not available from this repository.Abstract
In present studies the synthesis, characterization and biological properties of
oxovanadium(IV) coordination compounds of 4[N-(4′-ethylbenzalidene)amino] antipyrine
thiosemicarbazone (EBAAPTS) and 4[N-(2′,4′-dimethylbenzalidene)amino] antipyrine
thiosemicarbazone (DMBAAPTS) with the general composition VOX2L (X = C1-, Br-, I-, NO3- or NCS-) and VO(CIO4)2(L)H2O (L = EBAAPTS or DMBAAPTS) are described . All the complexes were characterized by elemental analyses, molar mass, molar conductance, magnetic susceptibility, infrared and electronic spectra. In all these complexes, both the thiosemicarbazones behave as neutral tridentate (N, N, S) ligands. The thermal properties of the representative complexes are also reported. The most probable geometry of the complexes is proposed.
Item Type: | Journal Article |
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Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Science, Technology and Environment (FSTE) > School of Biological and Chemical Sciences |
Depositing User: | Ms Neha Harakh |
Date Deposited: | 24 Nov 2009 00:34 |
Last Modified: | 29 Mar 2012 08:54 |
URI: | https://repository.usp.ac.fj/id/eprint/1448 |
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